Hi,
You can Add this to your Style.Resources, to color the Background of the PropertyItem :
-Xceed.Wpf.Toolkit/PropertyGrid/Themes/Aero2.NormalColor.xaml.cs (for windows8)
-Xceed.Wpf.Toolkit/PropertyGrid/Themes/Generic.xaml (for windows7)
Issue https://wpftoolkit.codeplex.com/workitem/20755 has been created to be able to customize the Expander Color.
You can Add this to your Style.Resources, to color the Background of the PropertyItem :
<Style TargetType="{x:Type xctk:PropertyItem}">
<Setter Property="Background" Value="Green"/>
</Style>
For the Expander color, it is currently always Black. You will have to modify "GlyphBrush" in :-Xceed.Wpf.Toolkit/PropertyGrid/Themes/Aero2.NormalColor.xaml.cs (for windows8)
-Xceed.Wpf.Toolkit/PropertyGrid/Themes/Generic.xaml (for windows7)
Issue https://wpftoolkit.codeplex.com/workitem/20755 has been created to be able to customize the Expander Color.